AIUPPA, A., BITETTO, M., RIZZO, A.L., VIVEIROS, F., ALLARD, P., FREZZOTTI, M.L., VALENTI, V., ZANON, V. (2020) - The fumarolic CO₂ output from Pico do Fogo Volcano (Cape Verde). Italian Journal of Geosciences, 139: 325-340, doi: doi.org/10.3301/IJG.2020.03.

​The Pico do Fogo volcano, in the Cape Verde Archipelago off the western coasts of Africa, has been the most active volcano in the Macaronesia region in the Central Atlantic, with at least 27 eruptions during the last 500 years. Between eruptions fumarolic activity has been persisting in its summit crater, but limited information exists for the chemistry and output of these gas emissions. Here, we use the results acquired during a field survey in February 2019 to quantify the quiescent summit fumaroles' volatile output for the first time. By combining measurements of the fumarole compositions (using both a portable Multi-GAS and direct sampling of the hottest fumarole) and of the SO₂ flux (using near-vent UV Camera recording), we quantify a daily output of 1060±340 tons CO₂, 780±320 tons H2O, 6.2±2.4 tons H₂S, 1.4±0.4 tons SO₂ and 0.05±0.022 tons H₂. We show that the fumarolic CO₂ output from Pico do Fogo exceeds (i) the time-averaged CO₂ release during 2015-type recurrent eruptions and (ii) is larger than current diffuse soil degassing of CO₂ on Fogo Island. When compared to worldwide volcanoes in quiescent hydrothermal-stage, Pico do Fogo is found to rank among the strongest CO2 emitters. Its substantial CO₂ discharge implies a continuous deep supply of magmatic gas from the volcano’s plumbing system (verified by the low but measurable SO₂ flux), that becomes partially affected by water condensation and sulphur scrubbing in fumarolic conduits prior to gas exit. Variable removal of magmatic H₂O and S accounts for both spatial chemical heterogeneities in the fumarolic field and its CO₂- enriched mean composition, that we infer at 64.1±9.2 mol. % H2O, 35.6±9.1 mol. % CO 0.26±0.14 mol. % total Sulfur (S ), and 0.04±0.02 mol. % H₂.